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Chem. 26, 1 2 1 1 ( 1 9 5 4 ) . 25. MILLER D . M . : Can. J. Chem. 33, 1 1 8 4 ( 1 9 5 5 ) . 2 6 . HODGSON H . W . , GLOVER J. H . : Analyst 76, 3 8 0 ( 1 9 5 1 ) . 2 7 . KRYUKOVA T. Α . , SiNYAKOVA S. J . , AREFYEVA T . V . : Polyarograficheskii analiz, p. 1 3 4 . Na- uchnotekhn. izd. khim. literatury, Moscow 1 9 5 9 . Literature 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 51 JENTZSCH D . : Chem, Tech. (Berlin) 5, 221 (1954). : Chem. listy 47, 969 (1953); Collection Czechoslov.

Literature p. 72 70 V. Migration Currents The increase in limiting current due to migration during cathodic reduction of cations and anodic depolarization of anions above the pure diffusion current cannot be used in practical polarography because the migration component of the current is too sensitive to additions of foreign electrolytes. Only with a 25 —50 ~ fold excess of an indifferent electrolyte does the mean Umiting current attain a constant value (mean limiting diffusion current) that is no longer affected by adding more indifferent electrolyte.

76, 5221 (1954). 82. LEE T . : J. Am. Chem. Soc. 74, 5001 (1952). 83. KOLTHOFF L M . , ANASTASI H . , TAN B . H . : J. Am. Chem. Soc. 80, 3235 (1958). 84. GRIFFITHS V . , PARKER W . : Anal. Chim. Acta 14, 194 (1956). 85. ADAMS R . N . : Progress in Polarography. P. ZUMAN, L M . KOLTHOFF, Ed. V o l . , p. 503. , New York 1962. 86. MUELLER T . R . , OLSON C . L . , ADAMS R . N . : Advances in Polarography. I. S. LONGMUIR, 87. 88. 89. 90. 91. 92. Ed. Vol. , p. 198. Pergamon Press, London 1960. MUELLER T .

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