By Frederick G. Mann, Arnold Weissberger
The Chemistry of Heterocyclic Compounds, because its inception, has been well-known as a cornerstone of heterocyclic chemistry. every one quantity makes an attempt to debate all facets – homes, synthesis, reactions, physiological and business importance – of a selected ring process. to maintain the sequence updated, supplementary volumes overlaying the hot literature on each one person ring process were released. Many ring structures (such as pyridines and oxazoles) are taken care of in certain books, each one along with separate volumes or elements facing various person issues. With all authors are famous professionals, the Chemistry of Heterocyclic Chemistry is taken into account world wide because the crucial source for natural, bioorganic, and medicinal chemists.
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Additional resources for Heterocyclic Derivatives of Phosphorous, Arsenic, Antimony and Bismuth (The Chemistry of Heterocyclic Compounds, Volume 1, 2nd Edition)
The mass spectrum shows a molecular ion at mle 752, of composition C48H30N6Pz,determined by high resolution ; the compound must be an adduct of three molecules of dicyanoacetylene and two of triphenylphosphine. Consideration of the full mass-spectrometer results, of the ultraviolet spectrum, and of the Ph3P< NC ,c-c -,CN + NC Part I 36 chemical analysis indicates that the compound is 1,6-bis(triphenylphosphoranylidene) - 2,4- hexadiene - 1,2,3,4,5,6 - hexacarbonitrile (49). This is probably formed by the combination of the initial reactants to which then combines with a give the 1: 1 dipolar intermediate (M), second molecule of the acetylene to give an extended dipolar intermediate (51) ; combination of (50) and (51) then gives the final product (49).
Cookson, Hocking, and Hughes 2 3 ) . A recenti simple synthesis of the phosphole system (Mark1 and Potthast 21) has two variations. (a)When various 1,4-butadiynes (15; where R is an aryl or an alkyl group) are added t o a solution of bis(hydroxymethyl)phenylphosphine, C6H6P(CHzOH)2, in anhydrous pyriRC=CkCR dine, which is then boiled for 5 hours, the corresponding %,5-disubstituted 1-phenylphosphole (16)usually crystallizes out. ( b ) When the butadiyne (15) is added to a cold solution of phenylphosphine in benzene or benzene-tetrahydrofuran containing a catalytic quantity of phenyllithium, a vigorous initial reaction may occur; the reaction mixture, after 18 hours a t room temperature, gives the phosphole (16)on distillation.
161-163";this did not undergo EL Wittig reaction with cyclohexanone. p. 5", identified by its nmr spectrum aa 2-methyl-1,2,5-triphenyl-3-phospholene l-oxide (a), which, it is suggested, arose from the unstable three-membered ring system (42) ; catalytic hydrogenation of (43) gave the corresponding phospholane. The products formed by the action of the triphenylphosphole and its 1-oxide with methyl diazoacetate varied considerably with the conditions. (a)The phospholc in boiling dioxan containing copper powder gave the dimebhyl ester (39), presumably by intermediate decomposition of the diazoacetate to dimethyl fumarate.