By Marlene A. Deluca

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The CL which is luminol enhanced probably occurs from peroxidases, lipoxygenases and cyclooxygenase (21). MAJOR DEFECT IN SODIUM MOVEMEN FMLP PEPTIDE 2. SECONDARY DEFECT IN (CALCIUM CALCIUM NO ACTIVATION DEPOLARIZATION NO CL DEPENDENT) CA*'1, IONOPHORE A 23I87 DEPOLARIZATION--- NO CL FIGURE 5. VIII. Depolarization defects chronic-granuloma tous in granulocytes of disease patient. DEPOLARIZATION DEFECTS IN DISEASE Chronic Granulomatous Disease granulocytes (CGD) have been shown to be defective in depolarization of the granulocyte membrane (14) .

Dr. Schuster Do you think that it's necessarily true that the radiative lifetime in solution is the same as the radiative lifetime in the gas phase for singlet oxygen? Dr. Foote A most interesting point on which I would like to see some evidence. Dr. Kasha There is a point, Chris, about that which I don't have any quantitative information at hand, but the electronic mechanism for exciting singlet delta oxygen changes. The radiative lifetime that we are quoting, the 45 minute lifetime, is for the magnetic-dipole mechanism.

We investigated the possibility that the formation of a ground state complex between dioxetanone 1 and certain metalloporphyrins is the cause of the unusual catalysis. We used tetramethyldioxetane (2) as a model for 1. 0 nm. 2 nm. A similar result is obtained with MgTPP. Interestingly, AgTPP, which does not readily expand its coordination sphere (14), and for which no special catalysis is observed, does not give evidence of complex formation with dioxetane 2. This is in line with our observation that even pyridine does not shift the absorption maximum or oxidation potential of this metalloporphyrin.

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